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Love Canal, Superfund Birthplace EarthCache

Difficulty:
2.5 out of 5
Terrain:
1.5 out of 5

Size: Size:   not chosen (not chosen)

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Geocache Description:

Love Canal, our nations first EPA "Superfund" site. Posted coordinates are for a parking area. This earthcache will take you to the infamous "Love Canal" the first EPA "Superfund" site.
Congrats to FerrisFamilyof5 on their First FTF!!
Congrats to Tucci's Team on the STF and their 1300th find!



The Love Canal disaster is a dramatic example of chemical migration.

Migration - The movement of chemicals or elements in soil or groundwater, usually influenced by gravity and the porosity and permeability of soil and rock.

Porosity

Simple Definition - A property of rocks describing the volume of pore space relative to the total rock volume. Degree to which soil, gravel, sediment, or rock is permeated with pores or cavities through which water or air can move.

Long Definition - Used in geology, hydrogeology, soil science, and building science, the porosity of a porous medium (such as rock or sediment) describes the fraction of void space in the material, where the void may contain, for example, air or water. It is defined by the ratio: \phi = \frac{V_V}{V_T} where VV is the volume of void-space (such as fluids) and VT is the total or bulk volume of material, including the solid and void components. Both the mathematical symbols f and n are used to denote porosity. Porosity is a fraction between 0 and 1, typically ranging from less than 0.01 for solid granite to more than 0.5 for peat and clay, although it may also be represented in percent terms by multiplying the fraction by 100. The porosity of a rock, or sedimentary layer, is an important consideration when attempting to evaluate the potential volume of water or hydrocarbons it may contain. Sedimentary porosities are a complex function of many factors, including but not limited to: rate of burial, depth of burial, the nature of the connate fluids, the nature of overlying sediments (which may impede fluid expulsion). One commonly used relationship between porosity and depth is given by the Athy (1930) equation: \phi(z) = \phi_0 e^{-kz}\, where f0 is the surface porosity, k is the compaction coefficient (m-1) and z is depth (m). A value for porosity can alternatively be calculated from the bulk density ?bulk and particle density ?particle: \phi = 1-\frac{\rho_{\text{bulk}}}{\rho_{\text{particle}}} Normal particle density is assumed to be approximately 2.65 g/cm⊃3;, although a better estimation can be obtained by examining the lithology of the particles.


Permeability

Simple Definition - The rate at which liquids pass through soil or other materials in a specified direction.


Long Definition - In the earth sciences, permeability (commonly symbolized as ?, or k) is a measure of the ability of a material (typically, a rock or unconsolidated material) to transmit fluids. It is of great importance in determining the flow characteristics of hydrocarbons in oil and gas reservoirs, and of groundwater in aquifers. The intrinsic permeability of any porous material is: {\kappa}_{I}=C \cdot d^2 where ?I is the intrinsic permeability [L2] C is a dimensionless constant that is related to the configuration of the flow-paths d is the average, or effective pore diameter [L] Permeability needs to be measured, either directly (using Darcy's law) or through estimation using empirically derived formulas. A common unit for permeability is the darcy (D), or more commonly the millidarcy (mD) (1 darcy \approx10-12m2). Other units are cm2 and the SI m2. Permeability is part of the proportionality constant in Darcy's law which relates discharge (flow rate) and fluid physical properties (e.g. viscosity), to a pressure gradient applied to the porous media. The proportionality constant specifically for the flow of water through a porous media is the hydraulic conductivity; permeability is a portion of this, and is a property of the porous media only, not the fluid. In naturally occurring materials, it ranges over many orders of magnitude (see table below for an example of this range). For a rock to be considered as an exploitable hydrocarbon reservoir without stimulation, its permeability must be greater than approximately 100 mD (depending on the nature of the hydrocarbon - gas reservoirs with lower permeabilities are still exploitable because of the lower viscosity of gas with respect to oil). Rocks with permeabilities significantly lower than 100 mD can form efficient seals (see petroleum geology). Unconsolidated sands may have permeabilities of over 5000 mD.

The name Love Canal came from the last name of William T.Love, who in the early 1890s envisioned a canal connecting the two levels of the Niagara River separated by Niagara Falls. He believed it would serve the area's burgeoning industries with much needed hydroelectricity; however, the power scheme was never completed due to limitations of DC power transmission, which was the only means of delivering electricity at the time.

Only one mile (1.6 km) of the canal, about 15 feet (5 m) wide and 10 feet (3 m) deep,stretching northward from the Niagara River, was ever dug.

By the 1940's, a company by the name of Hooker Chemical and Plastics Corporation began a search for a dump to store the increasing amount chemical waste it was producing. Finding Love Canal ideal, Hooker Chemical made arrangements with the local power company, then-owner of the site, to dump its waste there. They prepared the canal for the waste by draining it and lining it with clay. Into this Hooker began placing fifty-five gallon metal barrels. In 1947, Hooker bought the land outright.
Source Berton, Pierre. Niagara: a history of the falls. McClelland& Stewart Inc. 1994.

At the time of the closure of the site, in approx. 1952-53 Niagara Falls' population had begun to expand. The local school board was desperate for land, and attempted to purchase an area of expensive property from Hooker Chemical that had not yet been used to bury toxic waste.The corporation refused to sell on the grounds of safety, and took members of the school board to the canal and drilled several bore holes through the clay, showing that there were toxic chemicals below the surface. However, the board refused to capitulate. Eventually, faced with the property being condemned and/or expropriated, Hooker Chemical agreed to sell on the condition that the board buy the entire property for one dollar. In the agreement, Hooker included a seventeen line caveat that explained the dangers of building on the site:

“ Prior to the delivery of this instrument of conveyance, the grantee herein has been advised by the grantor that the premises above described have been filled, in whole or in part, to the present grade level thereof with waste products resulting from the manufacturing of chemicals by the grantor at its plant in the City of Niagara Falls, New York, and the grantee assumes all risk and liability incident to the use thereof. It is therefore understood and agreed that, as a part of the consideration for this conveyance and as a condition thereof, no claim, suit, action or demand of any nature whatsoever shall ever be made by the grantee, its successors or assigns, against the grantor, its successors or assigns, for injury to a person or persons, including death resulting therefrom, or loss of or damage to property caused by, in connection with or by reason of the presence of said industrial wastes. It is further agreed as a condition hereof that each subsequent conveyance of the aforesaid lands shall be made subject to the foregoing provisions and conditions.

Shortly thereafter, the board began construction on the 99th Street School in its originally intended location. However, the building site was forced to relocate when contractors unearthed two pits filled with chemicals.
The new location was directly on top of the former landfill, and during construction, contractors broke through the clay seal that Hooker had installed to contain the chemical waste.
In 1957, the City of Niagara Falls constructed sewers for a mixture of low-income and single family residences to be built on lands adjacent to the landfill site. During construction of the gravel sewer beds, the clay seal was broken again, the walls of the canal were breached, and chemicals seeped from the canal. The construction of the LaSalle Expressway restricted groundwater from flowing to the Niagara River.
Following the wet winter and spring of 1977, the elevated expressway turned the breached canal into an overflowing pool.
Source - Zuesse, Eric (February 1981). Love Canal: The Truth Seeps Out. Reason Magazine.

The three requirements for this earthcache are;
1. Take a photo of yourself with you GPS at either the sign at N 43.05.018, W 078.57.120 OR The intersection of 99th St and Colvin Blvd, with the street signs in the background.
2.Email me either the uninhabitable acreage enclosed by Colvin Blvd., 100th St., Frontier Ave. and 95th St. or the length of the perimeter of that area. DO NOT POST THAT INFO IN YOUR LOG
3. Measure the distance of chemical migration from the WEST edge of the fenced off area (Old Canal)WEST to the nearest habitable street (street with occupied housing) to the WEST of the impact zone and e-mail that information to me as well. Again, DO NOT POST THAT INFORMATION IN YOUR LOG. Any logs without the required photograph and email may be deleted without warning.

Also, while you are here, you might want to check out GCGRN8 Love Canal Revitalized by Barbershop Dru as well as the waymark by Dru.
I have earned GSA's highest level:

Additional Hints (Decrypt)

Lbhe TCF znl unir na nern pnyphyngvba shapgvba. Lbh znl arrq gb gnxr na nqqvgvbany jnlcbvag.

Decryption Key

A|B|C|D|E|F|G|H|I|J|K|L|M
-------------------------
N|O|P|Q|R|S|T|U|V|W|X|Y|Z

(letter above equals below, and vice versa)