Please see:
Bond 01 - Dr. No
for a list of caches in the series.
Movie #: 05
Title: You Only Live Twice
Year: 1967
Bond: Sean Connery
Villain: Blofeld - SPECTRE #1 (Donald Pleasance)
Woman: Kissy - Bond's Japanese wife (Mie Hama)
Song: You Only Live Twice, performed by Nancy Sinatra.
Memorable gadget: "Little Nelly", a portable helicopter from Q that fits in 4 suitcases.
Memorable character: Tiger Tanaka, Japanese Intelligence. Kidnaps Bond and slides him down a chute into his office. Introduces Bond to the Japanese way of life.
Memorable quote: In this movie, Bond fakes his own death. As a police officer discovers him dead, he states "Well at least he died on the job. He'd have wanted it that way."